those Countries has an electoral-college type system? Does anyone have a list like this?
There are probably a lot of them
Doing it for Spanish elections is somewhat tough since the "states" would be the 17 autonomous communities, but both Congress and the senate assign their seats to the provinces. And in the islands it's even harder because of the Senate constituencies there being the islands, not the provinces.
In any case, here's my rough approximation using the Congress seats+Senate seats in each province, for the Canary/Balearic Islands, they are treated separately, so there are say, 7 Congress EVs and then each island gets then 1 or 3 Senate EVs (kind of like how Maine/Nebraska split their votes).
A sideffect is that since the Congress/Senate ratio is closer than in the US (350/208 instead of 435/100) smaller provinces will be even more overrepresented (thus, more "unfair winners")
(558 EVs, 280 to win).
For Spain I found:
1993:Lorenzo Olarte (CC): 3 (Lanzarote, Fuerteventura, El Hierro senate)Iñaki Anasagasti (PNV): 14Miquel Roca (CiU): 17Jose María Aznar (PP): 257Felipe González (PSOE): 267PSOE: 38.9%PP: 34.8%Technically PSOE still wins, but it would go to the house since no candidate would have a majority because of nationalist spoilers. The House may or may not elect González but it probably would. If we are doing VP elections in the Senate as well, same thing would go for VP Narcís Serra.
2004Paulino Rivero (CC): 2 (La Palma, El Hierro senate)Josu Erkoreka (PNV): 23Jose Luis Rodríguez Zapatero (PSOE): 226 (includes Lanzarote senate)Mariano Rajoy (PP): 307PSOE: 42.6%PP: 37.7%Rajoy wins even though Zapatero wins the popular vote (and by a substantial margin at that).
2008Ana Oramas (CC): 1 (El Hierro senate)Jose Luis Rodríguez Zapatero (PSOE): 270Mariano Rajoy: 287 (includes Mallorca and Fuerteventura senate)PSOE: 43.9%PP: 39.9%More of the same as in 2004.
Seems like Zapatero just ran up the margins against PP in the traditionally nationalist Catalonia and Basque Country. Rajoy got a miserable 6.5% in Barcelona for example!
Fun fact: I once calculated a "what if Catalonia didn't exist" scenario and 2008 was the only election where the results changed (even in 2004 PSOE managed to still eke out a narrow win).