Can one state get 100 EVs?

[YE]

That would require a state to have 22.5% of the country's population. California could do it, but that day is a long way away.

Any state with than proportion of the population should split itself.

Or smaller states should be merged. I've always found 50 states to be far too many.

CT-RI-MA and VT-NH-ME megastates.  They are way too tiny.

MA and CT aren’t exactly small states.