Early returns from Indiana and Kentucky between 6 and 7 PM EST will indicate whether Trump is under-performing in Republican counties. Early returns from Florida between 7 and 8 PM EST will also be telling. I imagine states like Pennsylvania and Virginia where she is leading will not be called immediately just in case there is some hidden Trump vote, but we should know before 9 PM EST how the two candidates are performing in relation to polling and it will be clear who is going to win unless the race has drastically toghtened.
Problem with VA is that NoVa, especially Fairfax, is really slow to count. It is likely that Trump will have a lead in the state early on in the night.
I'm curious why that is. It's densely populated and near a global data hub.
Here in Arlington, at least, we have a lot of very large precincts, and the state specifically cut off money to modernize the voting system several years ago (for a while, this meant there was a confusing mix of electronic voting machines and paper scantron-type ballots; we've since switched back to scantron entirely).
We also have a very large itinerant population, with resulting large swings in turnout that we aren't always well-prepared for; I believe we ran out of ballots on March 1.
As a result, expect long lines that mean voting won't be finished until well after 7PM, plus the by-hand verification of the results typically takes an hour or two.