Why didn't they go for Red-Red-Green in 2013?
The short answer:
The complete leadership ruled it out before the election back then repeatedly. The reasons they were listing were, that the Linke is unreliable and incompatible with the foreign policy of the SPD. Also a minority government tolerated by the Linke was ruled out.
The longer answer:
As we all know, these things do not need to hold after elections and the Linke actually tried to convince the SPD to change their mind.
You have to consider though, that the majority of a Red-Red-Green coalition would have been 5 seats (RRG having 320 and CDU/CSU 311). This is usually not that big of an issue, if the partners are really trusting each other and have similar policies. For example in NRW there is a Black-Yellow (CDU+FDP) coalition governing on state-level with a majority of just one seat and it works.
But in the case of RRG, there would for sure have been defectors. On the SPD side a few, because they did not want to have a coalition with or tolerated by the Left on principle. And in the Left/Linke there were still some SPD-hating MPs, which are mostly coming from Western Germany and were members of the WASG (a party which splintered away from the SPD during the Schröder-government and then united with the PDS to Linkspartei.PDS, which was later renamed to "Die Linke".) They were still angry at the SPD and there would have been a huge risk that some of them deflect, too, just to "show it to the SPD". (If you are interested in this topic google "Andrea Ypsilanti", to see an example).
Maybe it could have worked, maybe it would have failed. I say the chances that a Red-Red-Green coalition would have governed for the full term are pretty low, but still around 10%-30% (If I consider that they would have had to deal with the refugee-wave in 2015, these numbers probably are to optimistic).
Furthermore the SPD feared that they would be seen as breaking their word or being just hungry for power for every price. Plus you do need to consider how favorable Angela Merkel as chancellor was at this time.
Either was, they all three would have dropped in the polls if they had formed a government together. With good policy over the 4 years and a low amount of scandals, they may have recovered.
But again, there are a lot IFs involved in this.
Also the SPD did get the Union (CDU+CSU) to concede on suprisingly many of the SPD core issues, like the minimum wage, for example. So in the beginning the SPD thought they got a good deal there actually.
So from a strategic viewpoint the SPD certainly believed back then, that a GroKo would be the better choice for them.