Top 10 cities with the most people having Master's or Doctorate degrees1. Palo Alto, CA (housing, pop. 58,598): 26.3%
2. Bethesda, MD (housing, pop. 55,277): 24.6%
3. Brookline, MA (housing, pop. 57,107): 23.5%
4. Cambridge, MA (housing, pop. 101,355): 21.3%
5. Cupertino, CA (housing, pop. 50,546): 20.8%
6. Newton, MA (housing, pop. 83,829): 19.2%
7. Ann Arbor, MI (housing, pop. 114,024): 18.7%
8. Berkeley, CA (housing, pop. 102,743): 18.1%
9. Evanston, IL (housing, pop. 74,239): 17.4%
10. Mountain View, CA (housing, pop. 70,708): 16.8%
Top 10 cities with the most people having Doctorate degrees1. Palo Alto, CA (housing, pop. 58,598): 8.3%
2. Bethesda, MD (housing, pop. 55,277): 7.7%
3. Brookline, MA (housing, pop. 57,107): 7.1%
4. Cambridge, MA (housing, pop. 101,355): 6.3%
5. Davis, CA (housing, pop. 60,308): 5.8%
6. Ann Arbor, MI (housing, pop. 114,024): 5.3%
7. Berkeley, CA (housing, pop. 102,743): 5.2%
8. Newton, MA (housing, pop. 83,829): 4.8%
9. Ames, IA (housing, pop. 50,731): 4.6%
10. Cupertino, CA (housing, pop. 50,546): 4.1%
http://www.city-data.com/top2/toplists2.htmlSeveral Silicon Valley and Boston-area cities there, as expected, along with a few major university towns.