Culturally, again I think it would be similar to current NorCal/SoCal divides, but perhaps more pronounced. Which is to say, NorCal would feel even more like a northeastern state than it already does, and SoCal would be more Sun Belt-y than it already is.
I don't really think of NorCal as being culturally similar to any part of the Northeast- not least because California seems to define itself in opposition to the entire country east of the Rockies. Agree with you on the politics aspect.
True I think the PNW would have been a much more obvious comparison. Although a part of the reason why the PNW/NorCal are as progressive as they are was, historically, a mix of Yankee and Irish migration and general western populism. My understanding is that SoCal saw more Southern and later Midwestern/Plains (i.e. many conservative Germans) migration, again a bit more like Arizona, which created a more conservative culture in the mid-20th century. I could be wrong though, I'm a little rusty on California settlement patterns.