2100 is a bit far away, but the current trend is towards ever more, ever smaller, ever less powerful nations and ever fewer (er...no, probably not that one), ever larger, ever more powerful private corporations, and that'll continue for quite a while.
Increased cooperation between nations, regionally à la EU or worldwide à la UNO, will be the most powerful force against that, but won't mean actual fusing of nations, desirable as that may be.
Nothing much to add.
Oh, yeah, except: Given the massive economic and cultural problems (and political cleavages) created by every country merger these past hundred years or so, I think I'll lay off the "desirable as that may be" part.